Appendix E, Chemistry
2012-05-10 SPPwp
Please send comments to: J.Elfick@uq.edu.au
15.0.4 Low-cost chemicals
and common substances
Table of contents
Accumulator electrolyte, lead acid
battery electrolyte
Agar
Albumen, albumin
Alkaloids
Antacids
Anti-bumping granules
Antifreeze
Asphalt
Beeswax
Benzoic acid
Birdlime
Borax
Bottled gas, compressed gas, LPG, LP
Gas
Brass
Bronze
Buffer solutions
Butane gas
Camphor
Cellophane
Clay
Clinistix strip
Clove oil, eugenol
Coal gas
Cobalt chloride
Collagen
Collodion
Copper arsenite
Cornflour
Creosote
Cresylic acid
Cyanuric acid
DMSO
Desiccants
Ethephon
Eucalyptus oil
Evening primrose oil
"Gas"
Gases, (household gas, laboratory gas)
Gelatin, gelatine
Glass wool
Glazes
Hair
Household gas
Inks
Invertase
Isocyanuric acid
Javelle water
Laboratory gas, piped gas
Latex
Lavender oil
Lead antimonate
Lead compounds
Lemon oil
Linseed oil
Liver of sulfur
LPG (liquefied petroleum gas, LP gas)
Magnesium ribbon
Matches, safety matches
Metaldehyde
Methane gas,
Methylated spirits
Naphthalene
Natural gas
Neatsfoot oil
Paraffin oil, kerosene
Paris green
Pennyroyal oil
Petroleum jelly, (trade name), petroleum jelly
Producer gas
Propane gas
Putty
Resin, ion exchange resin
Safety equipment
Seawater substitute
Shellac
Soap
Solder
Starch
Tartar emetic
Talcum powder
Tannic acid and tea
Tea tree oil
Tincture of iodine
Town gas
Tung oil
Turpentine
Vanilla oil
Vaseline, (trade name), petroleum jelly
Vegetable oil
Water
Water gas
White spirit
Yeast
Gases (household gas, laboratory
gas)
Bottled gas compressed gas, LPG, LP
Gas
Butane gas
Coal gas
Household gas
Laboratory gas, piped gas
LPG (liquefied petroleum gas, LP gas)
Methane gas
Natural gas
Producer gas
Propane gas
Town gas
Water gas
Accumulator
electrolyte
Relative density of sulfuric is fully charged 1.28, half charged, 1.21,
discharged 1.15. Use safety glasses
and nitrile chemical-resistant gloves! Slowly add concentrated sulfuric acid,
with stirring, to a beaker two thirds full of distilled water, until the
solution is almost boils. Leave to cool and add more acid until the solution
almost boils. After cooling to room temperature, adjust the relative density
with more acid or more water, according to a hydrometer reading
Agar, agar agar, agar powder,
nutrient agar (beef broth + agar), tablets, powder, jelly-like substance
from red seaweed, agar nutrient, agar agar, isinglass, Macassar gum, gelatinous
substance, E406 Agar (from red algae, Phylum Rhodophyta) (vegetable
gum) (thickener, emulsifier), agar (potato) dextrose, cornmeal, isinglass,
Macassar gum
Albumen, albumin
Albumen,
egg white, white of an egg, albumen flakes, albumen egg powder. Albumin,
a protein that is soluble in water and can be coagulated by heat, (Also
serum albumins in blood serum and alphlactalbumin in milk, one of the globular
proteins)
Alkaloids
Basic organic nitrogen compounds in plants with powerful action on animals,
e.g. nicotine, morphine, quinine, strychnine
Antacids
Antacids increase pH in stomach contents as medicine for reflux, e.g.
sodium hydrogen carbonate NaHCO3, magnesium oxide MgO
Anti-bumping granules
Boiling chips, usually fused alumina also flower pot bits, prevents large
bubbles of gas forming that could cause explosive emissions from a beaker
containing a heated solution.
Antifreeze
An antifreeze depresses freezing point and raises boiling point. The term
"antifreeze" usually refers to ethylene glycol (monoethylene glycol, MEG),
(C2H6O2), (HOCH2CH2OH),
used in motor car cooling systems. However, it is toxic. Other antifreezes
include propylene glycol (C3H8O2, non-toxic
antifreeze), glycerol, (C3H8O3) and methanol
(CH3OH).
Asphalt
Bitumen, tar, pitch, black plastic solid final residues left after volatile
substances removed by fractional distillation
Beeswax
White and yellow beeswax, food additive E901, glazing agent, release agent,
for craft, modelling, ointments, polishes, from bee honeycomb mixture includes
the palmitic acid ester C15H31COOC30H61
Benzoic acid
Benzene carboxylic acid, C6H5COOH, preservative,
in creams for treating haemorrhoids
Birdlime
Birdlime, bird lime, inner bark of holly, mistletoe or elm branches, boiled
then evaporated to form a sticky substance used to trap small birds. Its
use is illegal in many places. It is not "lime", calcium oxide.
Borax, Na2B4O7.10H2O,
tdisodiumetraborate-10-water, E285, sodium tetraborate decahydrate but
commercial borax partially dehydrated , di-sodium tetraborate, tynkal, colourless,
mineral, white powder, odourless, monoclinic crystals or granules, r.d. 1.73,
m.p. 75oC, efflorescent in dry air, melts at 75oC,
anhydrous at 320oC, mildly toxic so avoid ingesting and skin
contact, (buffer solutions, fire retardant, metallurgy flux, washing powders
(laundry booster), bath cleaning, fungicide, insecticide, detergent booster,
preservative, but not allowed in most countries), used a lot in the furniture
industry.
E285 Sodium tetraborate, Borax (preservative) (not allowed
most countries) (toxic, may cause skin problems)
Borax and sugar mixture is used with cut lemon over ant trails to deter ants.
Borax, di-sodium tetraborate (III)-10-water, Local Purchase
Brass
Brass filings, (brass is mainly alloys of Cu and Zn, but Al, Fe, Mn, Ni,
Sn and Pb may be added)
Bronze
Bronze is mainly alloys of Cu and Sn but some may not contain Sn, e.g.
aluminium bronze, manganese bronze, bronze is in "copper" coins.
Bottled gas, compressed
gas
Gas in metal cylinders, under pressure, e.g. O2 and N2,
and liquefied under pressure, e.g. C4H10. UK standard
colours on cylinder shoulders, (EN 1089-3): black (N2), blue (N2O),
brown (He), dark green (Ar), grey (CO2), light blue (oxidizing
gas), maroon (C2H2), red (flammable gas), white (O2),
yellow (toxic gas and corrosive gas). See internet for colours in your country,
e.g. EU Compressed Gas Cylinder colour codes
Buffer solutions,
tablets, pH 4, pH 6.4, pH 8, pH 9.2,
Aluminium ammonium
sulfate, food additive E523, buffer, stabilizer
Boric acid, standard buffer solutions: 5.0
Buffer ampoules for 1000 mL pH 9.0, pH 7.0, pH 8.0, pH
9.0, pH 10.0
Buffer solution 500 mL colour coded for pH 10.0, pH 9.0,
pH 7.0, pH 9.2, pH 6.88, pH 4.0, pH 10.5
Buffer solutions pH 10 Colour coded blue
Buffer solutions pH 4 Colour coded red
Buffer solutions pH 7 Colour coded yellow
Buffer tablets pH 4.0
Butane gas
Butane gas, C4H10, 93.2, MJm-3, a liquefied
petroleum gas, (LPG), liquefied gas, bottled gas is liquefied butane, Calor
gas.
Butane isomer is 2-methylpropane, CH3CH(CH3)CH3,
formerly "isobutane"
Camphor
C10H16O, (synthetic, aromatic), highly flammable,
natural camphor from camphor laurel tree Cinnamomum camphora, (medicine, repels
clothes moths and cats, used to make gunpowder and celluloid), DL-Camphor
for moth balls, lotions, Celluloid is cellulose nitrate plasticized with
camphor, use camphor instead of moth balls to protect clothes from moths.
Cellophane
Modified
cellulose, (cellophane is a trade name, name from: cellulose + diaphane
(French: transparent), cellulose + alkali + carbon disulfide --> viscose,
viscose through sulfuric acid and sodium sulfate --> cellulose + glycerin
--> cellophane, rayon. Cellophane is used in food and cigarette packages,
"Sellotape", "Scotch Tape", dialysis tubing (Visking tubing)
Clinistix strip
Test for glucose, test for (+) glucose in urine, indicator substance o-toluidine
Clove oil, eugenol
Oil of cloves, eugenol, 2-methoxy-4-(2-propenyl) phenol, an allyl benzene
from dried flower buds (inhibits mould, relieves toothache, insecticide,
cooking ingredient, high concentration of antioxidants, spice, Indonesian
clove and tobacco cigarettes, fish killer, herbicide) toxic at low concentrations,
harmful if large quantity ingested, (eugenol also in nutmeg, cinnamon, bay
leaf), relative density
1.04 -1.06, so does not float on water, clove oil
contains eugenol and caryophyllene, used in dentistry, from Eugenia caryophyllus,
Myrtaceae.
Coal gas
Coal gas, (approx. 88 MJ /kg), approx. 50% hydrogen gas, 35% methane,
8% carbon monoxide, (poisonous gas), hydrogen cyanide and hydrogen sulfide,
(for a "safety smell"), lately synthetic natural gas, SNG, is synthesized
from coal or petroleum
Cobalt chloride, cobaltous chloride,
Cobalt (II) chloride,
CoCl2.6H2O, cobalt (II) chloride hydrated, cobalt
(II) chloride-6-water, cobalt chloride hexahydrate, Harmful if ingested,
Environment danger, hydrated
salt, pink, dark red deliquescent crystals, pink powder, acidic solution, CoCl2, (anhydrous salt blue,
test for water, humidity paper, in silica gel desiccant), blue borax bead
Collagen
Protein in animal connective tissue boiled to make gelatine glue, insoluble
fibrous protein in connective tissue, polypeptide chain mainly glycine and
proline, gristle, used for sausage casings
Collodion
Cellulose nitrate dissolved in a mixture of ethanol or diethyl ether,
cellulose tetranitrate, used as a medicinal coating. Also an early photographic
process, cellulose nitrate + soluble iodide coats a glass plate then in
darkroom immersed in silver nitrate to form silver iodide. Then the wet plate
was exposed in a camera, then developed with pyrogallic acid and fixed with
sodium thiosulfate or potassium cyanide solution.
Copper arsenite
Copper (II) acetoarsenite, yellow-green pigment, "Paris Green", is still
used as a poison and for green colour in fireworks. "Scheele's Green" is
no longer used, but its use in wallpaper may have killed the exiled Emperor
Napoleon Bonaparte on St. Helena Island!
Paris green, copper (II) acetoarsenite, (copper ethanoato-arsenate),
(Scheele's Green, Schweinfurth Green), POISON
Double compound of copper arsenite and copper acetate, bright blue-green
pigment, used as an agricultural chemical, wood preservative and ship anti-fouling
application. However, it is very poisonous and nowadays is thought to be too
dangerous to use.
Cornflour
Powdery starch synthesized from maize and used as a cooking thickener,
in USA "cornstarch", in Australia "wheaten starch". "Johnson's baby powder"
contains "pure cornstarch with aloe and vitamin E", i.e. Zea Mays
(corn) starch, Aloe barbadensis leaf juice, and tocopherol (Vitamin
E).
Crude oil
Petroleum distillate oil, unrefined natural petroleum
Creosote
Wood creosote, mixture of phenols of wood tar, (disinfectant, cough medicine,
diarrhoea medicine, preservative, antiseptic), coal tar creosote: (wood preservative,
fungicide, skin diseases, insecticide), may cause skin cancer
Cresylic acid is a mixture
of coal tar or petroleum byproduct phenols, disinfectant, Highly toxic
by all routes. Cresylic acid compounds are called cresol when the boiling
point is below 204°C. Cresols are mixtures of the ortho-, meta- and
para- isomers. Crude cresol contains approximately 20% o-cresol, 40% m-cresol,
and 30% p-cresol. Amber to red colour. Cresols are used to manufacture synthetic
resins, as degreasing compounds, paintbrush cleaner, fumigants in photographic
developers and explosives.
Any combustion process, which results in the generation
of phenolic compounds, e.g. automobile exhaust or coal, wood, or trash smoke,
may be a potential source of exposure to cresols.
Cyanuric acid
Cyanuric acid, (CNOH)3, H3C3N3O3),
is used in for swimming pools, purifying tablets, white soluble crystals,
solution converts to urea.
DMSO
Dimethyl sulfoxide, (CH3)2SO, (C2H6OS),
from wood pulp, oyster-garlic taste, (irritant, penetrates skin, horse
liniment, anti-inflammatory, paint stripper)
Desiccants
Drying agents, e.g. anhydrous calcium chloride, anhydrous calcium sulfate,
concentrated sulfuric acid, phosphorus (V) oxide, sodium hydroxide lump,
calcium oxide lump (lime), silica gel, glass desiccators used to dry chemicals
in the laboratory may have tap in the lid to increase evaporation by decreasing
pressure in the desiccator, can also preserve organic materials by desiccation.
Ethephon
Ethephon, 2-chloroethyl-dioxido-oxophosphorane, C2H6ClO3P,
(a phosphonate), decomposes to ethylene and dihydrogen phosphate, plant
growth regulator, used for cotton, pineapple, wheat, tobacco, coffee, kiwi
fruit, tomato grape, apple, sugar cane, apparently not a danger to environment.
Eucalyptus oil
Eucalyptol, C10H18O, 1,8-cineole, cyclic ether,
monoterpene, is a paint stripper, adhesive solvent, sticky spot remover,
flavouring, fragrance, mouth wash, anti-inflammatory, releases vapours for
medical use.
Evening primrose
oil
From Oenothera biennis, Onagraceae, common evening primrose, garden
herb, contains γ-linoleic acid.
Gases, lab gas, household
gas
In a laboratory, the pilot light should burn with a 90% blue flame. If
the flame is yellow, the gas may be contaminated with condensates. Do not
use such a gas but immediately inform the local gas authority. The heating
values of fuels: town gas 88 MJ / kg, natural gas 55.6 MJ / kg, LPG gas 49
MJ / kg, diesel fuel oil 38 MJ / L, kerosene 36.7 MJ / L, coke or coal 27
MJ / kg, dry split wood 12.5 MJ / kg.
Gelatin, gelatine
From collagen protein by boiling animal tissues, used as a glue, jelly
crystals, e.g. puragel, used in photographic emulsions, adhesives.
Glass wool
Glass wool is not recommended for use in school laboratories. Thin pieces
of glass wool can get into cuts and then into the blood stream. Do not touch
glass wool with the fingers, wear protective gloves. Do not breathe in glass
wool fibres. Do not reuse damaged glass wool. It may release fibre particles
into the air.
Glazes
Pottery glazes were formerly metal oxides, e.g. lead oxide and cadmium
oxide, often heavy metals, but most glazes nowadays have the metal oxide
fired with silica to form sintered glass. Glazes for school use must contain
no cadmium and < 0.1% lead dry weight.
Hair
Keratin is a fibrous protein occurring in hair, wool, feathers, hooves
and horns, imbedded in a matrix that makes them strong and elastic. The proteins
contain sulfur and are held together by disulfide bonds.
Inks
Inks include solvent-based
ink, water-based ink, ball pen refill, "Biro" or "Bic" refill, Indian
ink, variable toxicity, solvent may be flammable, marbling ink. Students
must not ingest marbling ink used in primary schools. Indian ink (Chinese
ink) is a mixture of lampblack, carbon black, bone black. For block
printing and screen printing do not use oil-based solvents, but use water-based
screen printing inks, e.g. "Lascaux".
Invertase
From baker's yeast, is a yeast extract enzyme, catalases sucrose hydrolysis
to fructose and glucose, harmful if ingested, irritates eyes, E1103, (stabilizer,
processing aid).
Isocyanuric acid
Isocyanuric acid is a chlorine stabilizer for swimming pools, administered
as sodium dichloroisocyanurate granules or trichloroisocyanuric acid tablets.
Javelle water
Aqueous solution of potassium or sodium hypochlorite, used as a disinfectant
and bleaching agent.
Latex, emulsion of rubber globules
in water, globules of synthetic materials, latex paints, male latex condom, latex tubing, natural polymer, vulcanization
Ficus elastica, Indian rubber plant, India rubber tree, [polyterpenes
in milky latex sap], Moraceae
Hevea braziliensis, natural rubber, para rubber, hevea rubber,
[polyterpenes with linked isoprene units, cis-1,4-polyisoprene, in milky
latex sap], Euphorbiaceae
Manilkara achras, sapodilla, chiku, chicle polyterpene, Mexico,
South America, desert fruit, latex chicle used, chewing gum, Sapotaceae
Manilkara bidentata, balata, latex used for non-elastic rubber,
sticky pulp eaten, Sapotaceae
Palaquium oblongifolium, latex
called gutta percha, polymer, natural trans-1.4-polyisoprene, same chemical
as natural rubber, polyisoprene, but with trans not cis bonding, Sapotaceae
Lavender oil
Lavender flower oil, mainly linalyl acetate, from Lavandula latifolia,
(insect repellent, dog inhibitor, air freshener, pain relief)
Lead antimonate
Naples yellow for craft, antimonate of lead
Lead compounds are cumulative
poisons. All lead salts are highly toxic if ingested or particles inhaled.
Wash hands after handling. Use < 10 mL or g per activity. Bright orange
pottery glazes usually contain lead salts. The pigments white 1, white 2, white 16, mixed white, chrome yellow, chrome
green, and chrome orange are highly toxic cumulative poisons.
Chrome red, PbO.PbCrO4, basic lead chromate
Chrome yellow, PbCrO4, lead chromate pigment
Crocoite, PbCrO4, Red lead ore
Lead paint detection kit to detect
lead in paint
Lead acetate, (See Lead (II) ethanoate)
Lead (II) bromide, PbBr2, lead bromide, Highly toxic by all
routes
Lemon oil
Oil from lemon peel, D-limonene, a terpene, (furniture polish, inhibits
spiders and insects, stain remover).
Light oil, sewing machine
oil
Sewing machine oil, WD-40 penetrating oil to prevent corrosion
Linseed oil
From seeds of flax Linum usitatissimum,
glycerides of oleic acid and other unsaturated acids. Used to condition
and seal bare wood in putty, paints, varnishes, for cricket bats, linoleum,
outdoor
furniture.
Liver of sulfur
Alkaline mixture of mainly potassium polysulfides that turns silver black.
LPG, LP Gas, Liquefied Petroleum
gas, is a clean burning fuel and is stored in gas cylinders as bottled
gas. LPG is a simple asphyxiant. It consists of propane (about 95%) together
with varying proportions of butane, propylene and butylene. A rank smelling
compound, odorant, e.g. ethyl mercaptan, is added so that the presence of
the gas can be easily detected. Incomplete combustion forms carbon monoxide.
Do not search for a gas leak with a lighted match or lighted taper. Use a
soap solution. Highly flammable, violently explosive mixture with air, toxic
if inhaled, purchased as cylinders containing the liquefied gas. Fill cylinders
by weight only. Hazchem Code 2YE. UN number 1075. Keep container upright
in well-ventilated place away from sources of ignition.
Magnesium ribbon
Magnesium powder is too dangerous for school use. Magnesium
powder dispersed in air is explosive and may explode on contact
with oxidizing agents, e.g. metal nitrates or chlorates, and should
not be combined with carbon tetrachloride, carbon dioxide, chlorinated
hydrocarbons, halogens.
Magnesium ribbon is easily ignited and burns very exothermically
almost instantaneously, with a white hot flame that emits UV radiation
and may cause eye damage. Use < 1 cm of magnesium ribbon in experiments.
Matches, safety matches
Match head: mainly potassium
chlorate and glue. Striking surface: mainly red phosphorus and powdered
glass. Safety match heads contain potassium chlorate, sulphur, fillers and glue.
Also strike-anywhere match heads contain potassium chlorate as an outside
layer on the phosphorus sesquioxide match head. Explosions based on collections
of match heads are not permitted in schools.
Metaldehyde
Metaldehyde is an ethanal tetramer formed by polymerization of ethanal,
acetaldehyde (CH3CHO)4 --> C4O4H4(CH3)4,
"meta" fuel, firelighter, canned heat, snail bait, "Esbit", "Blitzem".
Methane gas
Methane gas, CH4, natural gas, (55.6 MJ / kg), marsh gas. Natural gas is flammable gas, 99% methane, occurring
naturally underground, usually associated with petroleum
CH4 (g) + 2O2 (g) --> CO2 (g) + 2H2O
(g) + heat.
Methane is large proportion of coal gas, (firedamp in
coal mines, methane burns to form air depleted of oxygen called blackdamp,
choke damp)
Natural gas
CH4, C2H6, C3H8,
... It occurs usually over petroleum products so its composition varies.
Natural gas usually contains about 90% methane + various proportions of ethane,
propane, butane, nitrogen and carbon dioxide. It is odourless but during
manufacture a rotten egg rank smelling compound, e.g. a mercaptan, captan
(ethane thiol or ethyl mercaptan) may is added for gas detection. Incomplete
combustion produces carbon monoxide. It should burn with a 90% blue flame.
Check the colour of the flame in the pilot light is yellow, or a yellow condensate
forms on the nearby wall or the bottom of cooking pots have a black smudge,
ask the gas distribution authority for advice because the gas may be contaminated.
Be careful! Do not search for a gas leak with
a lighted match or lighted taper but use a soap solution.
Natural
gas is used in heating and cooking appliances, buses and other motor vehicles
and is transported by large tankers or gas grids. In many places it has replaced
town gas. All equipment using natural gas should be checked regularly. Use sturdy
undamaged tubing to connect Bunsen burners to gas taps. Replace any perished
tubing or tubing damaged at one end. Check that tubing is connected securely
to both the tap and the Bunsen burner before the gas is turned on. Clean
or replace any Bunsen burners that have damaged jets, or are known to burn
back. At the end of the school day, turn off the master gas switches in each
laboratory. Do not allow dangerous practices, e.g. turning on a gas tap and
then lighting it. If you smell an overpowering gas odour in a laboratory,
evacuate the area rapidly, open all windows and seek assistance.
Naphthalene, mothballs,
C10H8, m.p. 80.5oC, flakes, crystals,
marbles, balls, moth balls, Flammable
solid, Highly toxic by all routes
Naphthalene sublimes at room temperatures, toxic to humans in large doses,
high flammability, white substance, with a greasy feel and a peculiar penetrating
smell, insoluble in water but dissolves in methylated spirit, forms as a
by-product in the manufacture of coal gas. Uses include making dyes, protecting
clothes and carpets from moths and controlling insect pests in soil. It
is possibly carcinogenic, so other chemicals should be substituted to deter
moths and silverfish in the home, e.g. 1,4-dichlorobenzene, (paradichlorobenzene),
camphor, camphor laurel, Cinnamomum camphora, (Laurus camphora),
cedar, incense cedar, (Calocedrus decurrens), Spanish cedar (Cedrela
odorata)
Neatsfoot oil
Oil from boiled cattle hooves used as a leather conditioner for saddles,
boots, baseball gloves,
("neat " is old word for cattle).
Mineral oil
Lubricating light oil, diesel oil, distillation product of petroleum
Paraffin oil, kerosene
Paraffin, hard
paraffin wax (chunks), alkane mixture, CnH2n+2,
paraffin wax black 43 / 46 ("paraffins" was former name for "alkanes"), (paraffin, Latin parum,
little, affinis, related, because of its low chemical activity,
name invented by German chemist Karl Reichenbach in 1830)
Paraffin oil, kerosene, fp 60oC, (UK paraffin oil UK), (USA,
Australia, kerosene), (kerosine, "kero"), is a petroleum fraction containing
a mixture of hydrocarbons with 11 or 12 carbon atoms, mixture of hydrocarbons,
b.p range 150oC to 300oC), highly flammable solvent
and lamp fuel. Use in well-ventilated space, do not use as degreaser of engines.
Liquid paraffin (petrolatum liquid) is a pure mineral white oil emulsion
used as a medicine
Paraffin wax is alkanes C20H42 to C40H82. liquid paraffin is a pure mineral white oil emulsion
used as a medicine, paraffin wax is alkanes C20H42
to C40H82.Paraffin
wax used to make candles, polish, "wax" paper.
Paraffin liquid, liquid paraffin, colourless tasteless liquid form of
petroleum jelly, mixture of >C12 alkanes, ("Vaseline" (trade name), petrolatum,
white paraffin, is another
petroleum jelly.)
Paraffin, paraffin oil, kerosene, kerosine, mixture of C12H26
to C15H32, b.p. 16 - 250oC
Paraffin, paraffin wax, mixture of C20H42 and higher
molar mass hydrocarbons, m.p. 45 - 65oC, (commercial 52oC
pastillated), relative density 0.9
Paris Green
Paris Green, (Scheele's Green, Schweinfurth Green), is a double compound
of copper arsenite and copper acetate, copper ethanoato-arsenate. It is
a bright blue-green pigment It was used as an agricultural chemical, wood
preservative and ship anti-fouling application. However, it is very poisonous
and nowadays is thought to be too dangerous to use.
Pennyroyal oil
Pennyroyal oil, oil of pennyroyal, deters moths and fleas, from Mentha
pulegium, pennyroyal, Lamiaceae
Producer gas
Air gas. Similar to water gas, formed by passing air and steam over hot
carbon.
Propane gas
Propane gas, C3H8, a bottled gas, a liquefied petroleum
gas, (LPG).
Putty
Painter's putty, glazier's putty, paste of calcium carbonate, (whiting),
and linseed oil, sometimes white lead. used as a sealant or filler in glazing,
sealing glass into frames
Resin, ion exchange
Anion exchange resin, zeolite, ("Permutit")
Safety equipment
AS = Australian standard
Apron, Safety apron, PVC, (resists strong acids)
Ear protection, ear muffs, AS1270, general protection, 25 dB rated, class
4
Ear protection, ear plugs, Hilo 27 dB rated class 5, individually packaged,
box / 200 pairs
Ear protection, ear plugs, Hilo 24 dB rated class 5, in dispenser, box
/ 250
Eye-wash bottle, eye-wash cup
Face shield, Safety face shield (chemical, anti-splash face shield)
Face shield, moulded, lightweight, high impact and splash proof, visor
suits brow guard, (brow guard adjustable)
Face shield, small, adjustable, low impact and splash proof
Face shield, Black Eagle, clear visor, brow guard, chin guard, fully adjustable
Helmet, Safety helmet, ABS plastic, adjustable inner, AS 1801
Glasses, Safety glasses, safety goggles, (polycarbonate lens glasses)
Gloves, MSA Grand Prix, general purpose, beige leather, small, medium,
large
Gloves, disposable gloves, powder free and sulphur free polyethylene,
ambidextrous design unisize, suitable for food handling, catering and child
care
Gloves, Stretch vinyl medical gloves, non sterile powdered, small, medium,
large, box / 100
Gloves, Stretch vinyl medical gloves, non sterile powder free, latex free,
single use, small, medium, large, box / 100
Glove dispenser, three pack
Gloves, Mediflex nitrile gloves, disposable, blue, powder free with textured
fingers, small, medium, large, box / 100
Gloves, latex medical gloves, examination powder free, non sterile, beaded
cuff
Gloves, latex medical gloves, examination, powdered, non sterile, beaded
cuff
Gloves, N-DEX Ambidextrous Powdered Nitrile Gloves
Goggles, Safety goggles, chemical / dust goggle, close-fitted face seal,
self comfortable frame, anti-fog and anti-scratch lenses, certified to AS/NZS1337
medium impact protection
Goggles, Safety goggles, ChemPro, wide vision lens provides room for most
prescription spectacles, adjustable strap for individual fit, compatible
with most industrial head protection, anti-fog and anti-scratch lenses, certified
to AS/NZS1337 medium impact protection
Overalls, Safety overalls, Kleenguard XP protective overalls, low-linting,
antistatic, silicon free, suitable for hazardous dusts, chemical handling,
spray painting, pharmaceutical manufacturing electronic assembly
Overalls, Safety overalls, Kleenguard, polypropylene and microfibre, protect
against hazardous dust, particulate matter, repels water-based liquids, suitable
for agriculture, emergency services, maintenance
and cleaning duties
Respirators, MSA 2S, full face rubber mask, respirator, chemical resistant
rubber with polycarbonate lens with impact and chemical resistance
Spectacles, Safety spectacles, MSA Arctic Indoor, 100 % UV protection,
maximum glare reduction, certified to AS/NZS1337 medium impact protection
Spectacles, Safety spectacles, medium impact resistant, clear lens, will
fit over prescription glasses, adjustable arms with comfort cushions, certified
to AS/NZS1337 medium impact protection
Sun brim and neck flap, cool cotton brim with attached flap for maximum
sun protection, white, blue gloves, Safety gloves rubber, rubber safety gloves, (small/medium/large
rubber gloves), (rubber, caoutchouc)
First Aid kit, portable First Aid kit
Mask, surgical with ties, fluid resistant
Mask MSA Affinity, Reduce exposure to mechanically and thermally generated
dusts. mists, fumes and aerosols, as in crushing, blasting, grinding, welding,
soldering and refining processes
Mask, Dust mask, P1 filter, 3 panel flat fold design, for mechanically
generated particle, grinding, sanding, crushing sawing
Seawater substitute
Dissolve in 2 litres of water, 45.0 g sodium chloride, 3.5 g magnesium
sulfate, 5.0 g magnesium chloride, 2.0 g potassium sulfate.
Shellac
From resinous excretions of Coccus lacca or Tachardia lacca
scale insects, (varnish, polish, sealing wax, French polish is solution in
methylated spirit), E904. Solvent is highly flammable methylated spirits
that may irritate nasal surfaces.
Soap, bulk liquid soap, hand
soap bars, hand sanitizers, abrasive soap (contains sand)
Soap was formerly manufactured from beef and mutton fat, but nowadays mainly
vegetable oils are used, e.g. olive oil, palm oil, coconut oil. These oils
are compounds of glycerine with three organic acids, stearic acid, palmitic
acid, and oleic acid. When the fat or oil is boiled with sodium hydroxide
solution it splits into glycerine and the three organic acids. The organic
acids combine with the alkali to form soap, i.e. a mixture of sodium stearate,
sodium palmitate, and sodium oleate. Equation for stearic acid: glyceryl
stearate (fat) + sodium hydroxide --> glycerine + sodium stearate (soap).
When the boiling is complete the soap is precipitates and made to float on
the surface of the solution by adding salt. The soap is separated from the
underlying liquid and left to set. After it has dried it is cut to the needed
size, stamped, and packed.
Solder
Soft Pb and Sn alloys, resin-core solder, wire form, (Soldering flux,
soldering resin).
Starch, soluble starch, corn
starch, tapioca starch, sorghum gum, amylodextrin, amylopectin, amylum, arrowroot
starch, soluble laundry starch, starch gums adhesives, amylum, (C6H10O5)n,
where n = 40 to 50, farina, (test for iodine, forms blue colour). Starch,
like glucose, is a carbohydrate and contains carbon, hydrogen and oxygen
in the proportion C6H10O5, in a very complex
molecule.
Starch is present in nearly all plants. Potatoes, barley, wheat,
and rice are used as commercial sources. It is used for stiffening linen
in laundries, adhesive pastes and manufacture of glucose. Cornflour starch
is a powdery starch synthesized from maize and used as a cooking thickener,
in USA "cornstarch", in Australia "cornflour" is actually "wheaten starch".
Tartar emetic
Crystalline compound, K(SbO)C4H4O6.½H2O,
poisonous but used as expectorant and to treat schistosomiasis.
Talcum powder
Hydrated magnesium silicate, (French chalk), serpentine, (meerschaum pipes
and soap), (fine abrasive, absorbent, lubricant)
Tannic acid and tea
Tannic acid is present in oak galls. Make a solution of tannic acid by
boiling cut pieces of oak galls in water. Tannic acid is sold as a brown
powder and was used in tannic acid jelly for burns dressings. Tea from Camellia sinensis, has a slightly bitter, astringent flavour.
Tea contains polyphenols, but tea does not contain tannic acid.
Tea tree oil
Oil of Melaleuca, terpinen-4-ol, from Melaleuca alternifolia, a
paperbark tree (antibacterial, cosmetic, antifungal, sunburn).
Tincture of iodine
The word "tincture" means add a small mount of a substance to the main
substance or a tinge of something added to the main substance to change
the colour. Tincture of iodine because sodium iodide added, iodine would otherwise
be insoluble, 2-7% KI or NaI solution in ethanol and water, about 2 g iodine
and 2 g sodium iodide in 100 mL in 40-60% ethanol, contains soluble triiodide
anion I3-, disinfectant, antiseptic and starch test,
nowadays often replaced commercially by povidone iodine, e.g. Betadine. Lugol's
iodine solution is elemental iodine and potassium iodide.
Town gas
Town gas was the main domestic gas, a mixture of coal gas and carburetted
water gas, energy density about 20 MJm-3, was previously used
on school laboratories, but nowadays the gas is usually natural gas, i.e.
mostly methane CH4, or LPG, bottled gas, mostly propane, C3H8.
Tung oil
From the nut of the tung oil tree, Aleurites fordii. Used to penetrate
wood and seal against moisture in paints and varnishes. It dries hard.
Turpentine
1. Mineral turpentine, "turps", is the cheapest solvent for oil-based
paint and ink solvent, mixture of petroleum hydrocarbons, avoid vapours,
eye and skin contact, toxic by all routes of exposure, highly flammable,
("Turpentine Odourless Thinner", "Turpenoid", are solvents with strong smelling
hydrocarbons removed so may be undetected), ("Turpenoid natural", is non-toxic,
non-flammable,
and an alternative to mineral turps).
2. True turpentine, vegetable turpentine, spirit of turpentine, wood turpentine,
gum spirits, gum turpentine, from pine trees, (FP 35oC), contains
terpenes, e.g. α-pinene and β-pinene,
C10H16, pleasant odour but possible skin irritant vapour,
less toxic than mineral turpentine, highly flammable and reacts violently
with chlorine gas and explosively with chlorine compounds, e.g. tin
(IV)
chloride. Terpenes have linked isoprene units as in natural rubber.
Rosin is a solid amber residue made by the distillation of turpentine using
pine stumps.
Vanilla oil
Vanilla essence, (food fragrance and flavour, deodorizer, creaming soda,
creamy soda), Vanilla planiflora (V. fragrans), vanilla vine,
Vanilla pompona, West Indian vanilla, Orchidaceae.
Vaseline
Vaseline (trade name), petroleum jelly, soft paraffin, white paraffin,
white petrolatum, saturated semi-solid of crystalline and liquid hydrocarbons,
carbon numbers < C25, made by dewaxing paraffinic residual oil, liquid
paraffin is a liquid form of petroleum jelly, mixture of alkanes > 12
C atoms / molecule,
colourless, tasteless, mild laxative, popular low-cost
lubricant but weakens latex in condoms.
Vegetable oil
Castor oil, linseed oil, olive oil, "vegetable" oil, "salad" oil
Water
Tap water, deionized or demineralized water, distilled water, hard water,
soft water
Water gas
Water gas is a mixture of carbon monoxide and hydrogen gas. Water gas forms
when steam passes over hot coke or carbon.
White spirit
Stoddard solvent, dry cleaning fluid, "Murlex", mixture of aliphatic and
alicyclic C7 to C12 hydrocarbons, (cleaning solvent, paint thinner, remove
oil stains, clean oil-based paints from paint brushes).
Yeast, Dried yeast, (active
granules), baker's yeast, living yeast