School Science Lessons
Heat and temperature,
thermometers, melting point
and boiling point
2009-11-06
Please send comments to: J.Elfick@uq.edu.au
See: Interesting
websites
Table of contents
22.0 Heat and
temperature
22.1 Heat measuring devices, calorimeter
22.2 Heat sources
22.3 Thermometers,
temperature
22.4 Melting point and boiling point
22.5 Candle burner
22.6 Bunsen burner, "Gas-Pak"
22.0 Heat and temperature
2.8
Pressure affects the
boiling point
3.24
Air temperature (Primary)
4.10 Heat different solids
(Primary)
4.11 Temperatures during the day (Primary)
5.17 Body temperature (Primary)
6.3.1
SI, The 7 base units
6.3.1.5
Temperature,
Fahrenheit scale, Celsius scale, Kelvin scale
12.1.3
Pressure on solid ice
22.2.1 Heat has
no weight
22.2.3 Heat absorbed depends on mass
22.2.4 Heat dissipation
22.2.5 Heat a solid sphere and a
hollow sphere
22.1 Measuring devices, calorimeter,
measuring cylinder
1.28 Simple calorimeter
1.29 Measuring
cylinder / graduated cylinder
4.37
Heat and temperature
4.38
Calorific value of fuel
23.9.0.1 The units of
work and energy, joule and calorie
22.2 Heat sources
2.20 Spirit
burner (alcohol lamp)
(Primary)
8.1.3.1 Spirit burner, alcohol lamp
22.1.1 Simple heater
22.1.2 Drink-can charcoal burner
22.1.3 Make an alcohol lamp, spirit
lamp, from an
ink bottle
22.3 Thermometers,
temperature
4.14 Test a liquid in glass
thermometer
4.15
Thermoscope to compare
absorption of radiation
22.7.0 Thermometers
22.7.1 Temperature sense, feeling
"warm" and
"cold", measure temperature correctly only with thermometer
22.7.2
Expansion of liquid in a thermometer
22.7.3 Thermometer test, calibrate a
thermometer
22.7.4 Thermometers, 0oC to
100oC
range
22.7.5 Thermometer, make a thermometer
22.7.6 Thermocouple, thermistor,
constantan,
optical
pyrometer
22.7.7 Galileo's thermometer
22.7.8 Air thermometer
22.4 Melting point and
boiling point
7.4.0
Melting point, m.p. of solids
7.5.0 Boiling point, b.p. of liquids
7.7.5 Solubility of different salts
and temperature
22.5 Candle
burner
2.44 Candle flame (Primary)
4.9 Burning candles over water
6.35 Burn candle over water, candle
burning in inverted jar over water (Primary)
8.1.1.0
Candle, paraffin wax
8.1.1 1
Parts of a candle flame
8.1.1.2
Soot from a candle flame,
carbon
8.1.1.3
Describe dark region of
flame
8.1.1.4
Test gases from a wick
8.1.1.5
Aluminium foil below
candle flame
8.1.2.1
Prepare a beeswax candle
8.1.2.2
Burn two candles,
burning candle over water
8.1.2.3
Burning candle rocks to and
fro
8.1.2.4
Egg in a candle flame
22.6 Bunsen burner, "Gas-Pak"
2.11 Bunsen burner, "Gas-pak "
3.1.0 Bunsen burner
8.1.4.1
Bunsen burner, flame
8.1.4.2
Bunsen burner, flame, which part is hottest
8.1.4.3
Bunsen burner, flame can melt copper wire
13.2.1 Bunsen burner, flowing air can
do work, application of Bernoulli's law
2.8 Pressure
affects the
boiling point
Use a flask with a one-hole stopper with a thermometer in it. Fill a
flask 3/4 full with water, add boiling chip, heat until boiling, read
the
temperature, about 100oC. Invert the flask and hold it under
a cold stream of water. The water boils again. Read the temperature,
less
than 100oC. Again invert the flask and hold it under a cold
stream of water. The water boils again. Read the temperature, less
than
before. When the flask is cooled off with the cold water, water vapour
in the flask above the water condenses on the colder surface of the
flask,
a partial vacuum forms and the pressure inside the flask decreases.
Water
boils at 100oC at standard pressure, i.e. 760 mm mercury or
the pressure at sea level. If the pressure is lower the boiling point
is
lower. So it is hard to make a good cup of tea on a high mountain
because
the water boils at such a low temperature.
2.112 Temperature sense, feel temperature
Check if your temperature sense is reliable. Use containers of hot
water, warm water and cold water. Put both hands in the warm water. The
hands feel the same temperature. Put one hand in the hot water and the
other hand in the cold water. Quickly dry your hands and put them both
into the warm water again. The two hands do not feel the same
temperature.
Is your temperature sense reliable? This may be a silly experiment but
it shows that our temperature sense is not always reliable. You must
use
thermometers for experiments.
2.113 Thermometer, expansion of liquid in
thermometer
Fill a flask with coloured water. Insert a one hole stopper carrying
a 30 cm length of glass tubing until the water rises 5 cm in the
tubing.
Put the flask in a beaker of water. Heat the beaker and observe the
water
level in the tubing. The water rises in the tubing. However, if you
carefully
observe the water level in the tubing when the heating begins, you will
see that it falls slightly and then begins to rise! It falls because
the
glass in the flask starts to expand before the water inside. When the
heat
energy reaches the water it expands. So the expansion of liquid you see
in a thermometer is really the expansion of liquid less the expansion
of
the glass tube.
2.114 Spirit thermometer Experiment deleted!
Make a spirit thermometer by blowing a bulb in one end of the tubing,
inverting the open end of the tube in alcohol. Alternately heat and
cool
the bulb to draw alcohol into the tube, then calibrate in containers of
water of known temperature. However this activity is too dangerous for
schools especially when it comes to heat sealing the tube.
2.115 Test a thermometer
Use a thermometer with a scale, e.g. thermometer -10oC to
110oC mercury or alcohol, or a tall flask containing
coloured
water fitted with a one hole stopper and glass tube that extends into
the
bottle. Mark thermometer scales at two fixed points. The lower fixed
point is the temperature of melting ice. Put the bulb of a thermometer
in crushed ice that is melting. Leave it there for some minutes. Check
that the temperature is 0oC on the calibrated thermometer,
or
make a mark on the blank scale or on the glass tube attached to the
small
flask. The upper fixed point is the temperature of boiling water. Put a
thermometer in steam immediately above the surface of boiling water.
Leave
it there for some minutes. Check that the thermometer reads 100oC
on the calibrated thermometer, or make a mark on the blank scale or on
the glass tube attached to the small flask. Divide the distance
between the upper and lower fixed point to obtain marks representing a
temperature difference of 1oC. If you do the experiment on a
mountain at high altitudes the temperature of boiling water may be
below
100oC because of the reduced atmospheric pressure. If you do
the experiment in a submerged submarine the temperature of boiling
water
may be above 100oC. The thermometer in the boiling water
reads
exactly 100oC only at sea level or where the barometer
reading
is 760 mm of mercury.
Quantities of heat
2.135 Heat and temperature
Suspend a tin containing 50 mL water and a thermometer over a small
Bunsen burner flame or a candle. Record the initial temperature. Heat
it
for two minutes, constantly stirring, and record the final temperature
in degrees Celsius. Empty the water and repeat the experiment with 100,
150, 200 mL water, using the same flame. It is sufficiently accurate to
count 1 mL water as 1 g. Find the product of mass of water multiplied
by
rise in temperature in each case. As the same heat is given out by the
flame to each mass of water, the result suggests that a convenient unit
of heat would be that absorbed by 1 g water rising in temperature by 1oC.
This unit is called a gram calorie. You may see "Kilocalories" quoted
in
nutritional information, but the SI unit the joule, J, has replaced the
calorie. The 15o calorie is the heat to raise the
temperature
of 1 g water by 1oC at 15oC = 4.1855 J. So 1
calorie
= about 4.2 J. The joule, J, is the SI unit of work and
energy.
A joule is equal to the amount of work done when the point of
application
of a force of one newton moves one metre in the direction of the force.
1 joule = 107 ergs = 0.2388 calorie. The c.g.s. unit, the
calorie,
is the amount of heat required to raise the temperature of 1 gram of
water
by 1oC, i.e. 1K.
Nowadays the SI unit the joule, J, is used. 1 calorie = 4.1876
joules, commonly, 4.2 joules.
7.4.0 Melting point of solids
The melting point, m.p., is the temperature at which a solid starts
to liquefy. The melting point and freezing point of a pure substance
are
the same temperature. Melting is the "solid to liquid" type of phase
change.
Other phase changes include change from liquid to solid (freezing),
solid
to gas (sublimation), liquid to gas (evaporation), gas to liquid
(condensation).
Pure substances melt at constant temperature. Impurities lower the
melting
point. Impure substances, e.g. alloys, melt over a range of
temperature.
The melting point graph for a pure substance is horizontal as the solid
melts. The melting point graph for an impure substance has an inclined
line as the solid melts. Melting points and melting behaviours can be
used
to identify a substance and decide if it is pure. Melting is also
called
fusion and the melting point can be called the fusing point.
8.1.4.1 Describe the Bunsen burner flame
See diagram 3.1.1: Bunsen burner | See diagram 3.1.4: Bunsen burner and
candle flames
This type of gas burner has a gas jet at the base that draws air in
through the air hole because of the Bernoulli effect. It was invented
by
German chemist Robert Bunsen to improve the efficiency of combustion by
combining flammable gas from a jet with air before ignition to give a
very
hot flame. This premixed flame has a different structure to the
diffusion
flame of the candle. The blue part of the flame in inside the flame.
The
flame is conical because of the shape of the rim of the burner. The
premixed
flame burns efficiently with not much yellow flame or production of
soot.
1. Control the amount of air by opening and closing the air hole. Close
the
air hole. Turn on the gas. Light the gas. The flame is yellow. Hold a
piece
of wire in different parts of the flame to discover which part is the
hottest.
Hold a splint in different parts of the flame. The splint can be set
alight
in all positions in the yellow flame. Hold a test-tube just above the
flame.
Carbon is deposited on the glass. Test whether the unburned carbon
causes
the yellow colour of the flame by sprinkling powdered charcoal (carbon)
into the flame. Open the air hole. Mixing the air with the gas allows
the
gas to burn more rapidly and completely. The flame has an outer cone of
mainly blue flame and a colourless inner cone. The outer cone has a
thin
colourless area outside the blue flame. Hold a splint so that it passes
through the inner cone of the flame. The middle of the splint does not
burn because the inner cone is mainly unburned gas. Hold a piece of
wire
in different parts of the flame to discover which part of the flame is
the hottest. The tip of the colourless part around the outer cone is
the
hottest part of the flame. The temperature of different parts of a
Bunsen
burner flame can be measured with a thermocouple.
2. Test the inner cone of the flame
See diagram 3.1.3
Put one end of a piece of glass tubing in the inner cone of the flame.
Ignite the unburnt gases that come out of the other end of the tube.
8.1.4.2 Test which part of the Bunsen burner
flame is hottest
See diagram 3.1
Add 3 cm of water and small boiling chips to 3 test-tubes. Measure
the time taken to boil the water when the bottom of a test-tube is held
at the top of:
1. yellow flame (air hole closed), 2. non-luminous (dark blue) flame
(air hole open), 3. light blue flame (air hole open). The test-tube
held
at 3. boils the soonest.
8.1.4.3 Bunsen burner
flame can melt copper wire
See diagram 3.1
Bunsen burner flame can melt lead, m.p. = 327oC, and zinc,
m.p. = 419oC. Many people think the temperature of a flame
cannot exceed 500oC. Copper melts at 1085oC. It
is not usually considered possible to melt copper with a Bunsen burner
flame. The temperature of different parts of a non-luminous flame, a
blue flame, with the air holes fully open, vary. The hottest part of
the flame is at the tip of the central cone. The central core of the
flame contains a mixture of unburnt gas with air. The intense blue
region surrounding the central core is the main zone of combustion, in
which the gaseous hydrocarbon fuel reacts with the oxygen, forming
short-lived gases. The lighter blue outer flame is where these
short-lived gases are completely oxidized to carbon dioxide and water.
Copper metal reacts readily with oxygen from air when heated strongly,
forming a coating of black copper oxide, CuO. Under reducing
conditions, black copper oxide is reduced readily to metallic copper.
When heated strongly, but below its melting temperature, copper glows
with a bright red heat. To show that the maximum temperature reached,
you can melt copper use pieces of copper wire with three different
thickness found by stripping the insulation from electrical flex.
1. Light a Bunsen burner, turn the flame to maximum height, and open
the air holes so that the flame is completely blue. Hold a piece of
thick copper wire with tongs and probe the flame with the wire 1.
starting from the bottom 2. around the sides and tip of the central
cone, and 3. around the outer blue flame. At each place, record the
appearances of the copper, e.g. black, orange, red-hot, or tending to
melt.
2. Repeat the process with a thinner piece of copper, then with a
very thin piece of copper wire.
3. Reduce the flow of gas and repeat the procedures with a smaller
blue flame. The flame has six separate zones: Zone 1 is the core of
unburnt gas and air at the base of the flame. Zone 2 is the bright blue
region of intense combustion surrounding the core: zone 2A is the tip
of the central core, zone 2B is the region at the sides of the central
core. Zone 3 is the outer region of the flame where combustion becomes
complete: zone 3A is at the top of the flame, zone 3B is the outer part
of the sides of the flame. Zone 4 is the region just outside the flame.
At each zone observe the appearance of the copper, e.g. black, orange,
red-hot, tending to melt, three different thickness of wire. You can
melt fine copper wire in the flame but not thick copper wire.
12.1.3 Pressure on solid ice
Use 1 m thin strong steel wire, e.g. piano wire. Attach each end to
a broom handle. Loop the wire round a block of ice it and pull tightly
so that the wire exerts pressure on the ice. The pressure causes the
ice
to melt but when the pressure is released the ice becomes solid again.
Apply pressure and observe how the wire makes its way slowly through
the
ice. Similarly a knife forced against ice can exert pressure enough to
melt the ice at the edge of the blade. Force cubes of ice together then
see them join when the pressure is released and the melted ice freezes
again. An ice skater skates on a thin layer of water!
Heat sources
22.1.1 Simple heater
See diagram 22.1.1: Simple heating devices
Use a tin can cover and copper wire to make a handle under the rim
of a test-tube. Fill the can of hot water and place the can on a flame
to heat the can. Put some material into the test-tube then place the
tube
into the water at the can. At the liquid heater the material at the
bottle
may absorb quantity of heat round uniformly. If the material at the
test-tube
has a higher temperature fill the can of water with the same
temperature
to that of water at the tube the liquid heater becomes an effective
insulator.
22.1.2
Drink-can charcoal burner
See diagram 22.1.1: Simple heating devices
Prepare a large can of diameter at least 10 cm. Draw 6 small windows
of regular triangle uniformly on the side of the can and an angle of
each
triangle just up just towards the bottom of the can. Each window
locates
at the centre of the side of the can. For each triangular
window cut off the two lines of the angle downward then bend the
triangular
sheet back. The 6 triangular sheets form a stand in the can. Charcoal
may
be placed on the stand. Polish the windows with a file and drill some
air
holes. Now a stove has been made.
22.2.0 Heat and temperature, internal energy
and
heat, thermal physics, Thermal Properties of Matter, heat as a form of
energy, distinction between internal thermal energy, heat energy and
temperature,
heating as the process by which internal energy transfers occur as the
result of a temperature difference
See 23.9.0.1 The Joule / Calorie
Heat is a means by which energy can be transferred. The numerical value
for the heat is the amount of energy transferred. Internal energy is
the
energy associated with the total kinetic and potential energy of all of
the molecules of the object. If energy is transferred to an object its
internal energy rises. The internal energy would also increase if work
were done on the object. The SI unit of heat energy is the joule (i.e.
newton.metre). The extent to which an object will transfer or absorb
heat
(its hotness or coldness) is measured by temperature and is related to
the average kinetic energy of its molecules. The process by which the
energy
is transferred as heat as one of the following three: convection
conduction
and radiation.
22.2.1 Heat has no weight
The recognition of heat by people in history had experienced a long
and tortuous way. So called "heat mass" in general shows a unclear
recognition
to the character of heat. Heat is a form of energy
has no weight. However some students are probably think that heating a
beaker will somehow make it lighter. A few may believe that putting
"heat
in " somehow makes the beaker heavier! Hang a spoon in each end of the
cross arm in a stand thread tie to the spoon must be strong enough.
Adjust
the position of spoon to get them in exactly balance. Record these two
positions. Then remove the spoons. Heat one of the spoons by lifting it
over an alcohol burner. Put another spoon into cold storage in a
refrigerator
or cold water (if use refrigerator it is better not to put spoon into
freezer).
Place the two spoons back to the original position exactly note to
affirm
the cooled spoon is dry in advance and the position must be original
one.
To ensure not to confuse them it is better to select the two
spoons
which have different sizes and shapes or use different colour thread to
tie them. If every step is done the whole system is still in balance.
To avoid marking in cross arm to mark the original position the
cross
arm can be replaced by a meter.
1.28 Simple calorimeter
See diagram 22.1.1
1. Use a large-mouth glass bottle for example a large coffee bottle.
Use
a can with a top only able to be opened by a rotating knife to make
sure
that the outer rim on the top may be reserved in good order. and if
place
the bottle into the can make sure that the distance between the bottom
of the can and the bottom of the bottle must be more than the distance
between the outside of the can and the inner wall of the bottle. so
that
there is enough air between the can and the bottle to insulate heat.
Twine
a circle of a narrow piece of foam (or sponge) at the upper outside of
the can. Use white adhesive plaster to paste the foam to
prevent
the foam from slopping. Make a round cover with a white rigid used to
pack
instrument foam board (or middle density board). Do not use a scroll
saw
dig a round on the rigid plastic board. You may cut off a square first
with a knife cutting paper then cut it into a round. Use 0.15 cm wire
to
make a beater with a thermometer and brass wires. Drill a hole on the
cover.
To prevent heat loss paste a circle of silver paper metallic surface
inwards
then put some paper between the bottle and the can.
2. Simple calorimeter
Small soup tins can be found which fit loosely into a jam jar. If the
top of the tin is cut off cleanly with a rotary type opener it serves
as
an excellent calorimeter. The metal can be prevented from slipping into
the jar either by a stout rubber band round the edge, or by cutting
nicks
in the rim and bending it slightly outwards. This form of suspension,
and
the low conductivity of glass and air contribute to its efficiency.
Expanded
polystyrene, Styrofoam, drink cups are available in some countries and
make excellent calorimeters. Other suitable calorimeters can be made
using
two metal cans or glass beakers. Select containers so that one will fit
inside the other with at least 1 cm of space between them. Fill this
space
with glass wool or crumpled paper.
1.29 Measuring
cylinder / graduated cylinder
Select several straight sided glass jars of assorted sizes. Olive
bottles
are very useful for the making of graduated cylinders. Paste a strip of
paper about 1 cm wide vertically on the outside the bottle to within
about
a centimetre of the top. Next, obtain a commercial graduated cylinder
of
about the same capacity as the bottle and pour enough water from it to
fill the bottle nearly to the top of the paper scale. Draw a line
across
the paper scale and mark under it the number of cubic centimetres of
water
poured in. Repeat with lesser amounts of water to complete the scale.
22.2.3 Amount of heat absorbed depends on mass
Place a large iron bolt and a small nail in a beaker filled with
boiling
water. Fill other two beakers with equal masses of cold water at same
temperature
put a thermometer each. Note that the amount of water is better to just
immerse iron bolt. To do this you can test a suitable the amount of
water
by bolt before experiment. In the process of the experiment let large
iron
bolt and small nail are in boiling water for a while then take them out
of boiling water. Put large one into a beaker small one into another
beaker
rapidly. Observe the temperature of water rises record the temperature
in each beaker after temperature is stable. The different temperature
shows
the different amount of heat they have. The objects in different masses
at the same temperature absorb amount of heat which depend on their
mass
each.
22.2.4 Heat dissipation
Fill a small and a large round bottom flask with hot water at the same
temperature. Insert thermometers in both flasks and note the decrease
in
temperature as heat is dissipated. Heat dissipation is a function of
of
the area of the surface. Heat content is a function of he volume of the
unit. The area increases as the square of the radius but the
volume
increases as the cube of the radius.
22.2.5 Heat a solid
sphere and a hollow sphere
Put a solid metal sphere and a hollow metal sphere with the same
external volume in a beaker of water and heat the water. The expanded
external volumes are still the same. Put the two spheres in identical
beakers and add the same volume of water heated to the same
temperature. The hollow sphere expands more than the solid sphere
because its mass is less.
22.7.0 Thermometers
Thermometry, thermometers, temperature
scale, upper and lower fixed points, mercury thermometer, alcohol
thermometer,
clinical thermometer, liquid crystal thermometer
See diagram 22.02
A thermometer uses changes in a selected property to measure changes
in temperature e.g. change of length in thermostats change in volume in
mercury thermometers change in pressure in gas thermometers change in
resistance
of wires change in the emf in thermocouples. To calibrate a thermometer
in oC the value of the selected property is first found at
the
ice point and mark this 0oC. Then the value of the
property
is found at the steam point and mark this 100oC. Divide
the change in property between 0oC and 100oC into
100 equal parts each equivalent to a change in temperature of 1oC.
22.7.1 Temperature sense, feeling "warm" and
"cold", measure temperature correctly only with thermometer
See diagram: 22.02: Thermometers
1. Check if your temperature sense is reliable. Use containers of hot
water, warm water and cold water. Put both hands in the warm water. The
hands feel the same
temperature. Put one hand in the hot water and the other hand in the
cold water. Quickly dry your hands and put them both into the warm
water again. The two hands do
not feel the same temperature. This experiment shows that our
temperature sense is
not always reliable.
2. Fill three plastic dishes with the same amount of water but at
different
temperature 10oC, 20oC, 30oC. To get
water at different temperature more accurate first pour some
cold
water then put heat water stir lightly with a spoon to make temperature
evenly. Arrange three dishes from left to right with temperature from
low
to high. Let two students one put his right hand into 10oC
water
the other put his left hand into 30oC water. After two
minutes
take out their hands at the same time swing strength then put hands
into
dish at 20oC
in the middle simultaneously in time. Let each
student say the water in the middle dish is warm or cold. The
experiment
shows that you can judge if an object is warm or cold by our sensation.
However, this method is limited to a qualitative judge shows more
relatively
the degree of warm and cold of an object. The objects which have the
same
degree of warm or cold can be judged to a different conclusion of
degree
of warm or cold under different cases. You feel warmer as your hand
removes
from water in lower temperature to that of higher temperature while you
feel colder as your hand removes from water in higher temperature to
that
of lower temperature. As you can see warm and cold have not a definite
standard. This cannot meet the needs of showing degree of warm and cold
scientifically. To show the degree of warm and cold of an
object
quantitatively it is necessary to introduce an important quantity,
temperature
and make an equipment which can measure the temperature, the
thermometer.
22.7.2 Expansion of liquid in a
thermometer
1. Fill a flask with coloured water. Insert a one hole stopper
carrying a
30 cm length of glass tubing until the water rises 5 cm in the tubing.
Put the flask in a beaker of water.
Heat the beaker and observe the water level in the tubing. The water
rises in the tubing. However, if you carefully observe the water level
in the tubing when the heating
begins, you will see that it falls slightly and then begins to rise! It
falls because the glass in the flask starts to expand before the water
inside. When the heat energy reaches
the water it expands. So the expansion of liquid you see in a
thermometer is really the expansion of liquid less the expansion of the
glass tube.
2. Put some crushed ice in a Erlenmeyer
flask add a little water. The
depth of mixture in the flask is about one inch. Spin the flask to mix
water and ice. Insert a thermometer into the mixture. As the column of
liquid in thermometer is stable mark on thermometer beside the scale
marked
0oC. Put the flask on wire gauze on a tripod heat it with a
burner. As water in the flask boils mark again as 100oC.
Note
to maintain two marks at the same vertical line. The freezing and
boiling
point of water are primary standards for calibrating thermometer. Draw
a scale of thermometer between 0oC and 100oC
divide
it into 100 same space draw a longer line every 10 points written as 10oC
20oC draw a shorter line every 5 points written as 5oC,
15oC, 25oC. Compare the scale you have done to
original
one. Maybe they quite different. The main reason is the scale lines of
100oC are not the same because the atmospheric pressure is
not
the standard as you do the experiment and the boiling point of water
may
not exactly the 100oC. To draw line and calibrate
easily
you can use a sheet of coordinate paper stick to the thermometer in
advance.
22.7.3 Thermometer test, calibrate a
thermometer
There are two marked points on the scale of a thermometer. If a
thermometer
can measure the temperature from 0oC to 100oC the
two fixed points are at 0oC and 100oC. 0oC
is the melting point of ice and 100oC is the boiling point
of
water. Other scales of temperature are all defined refer to two fixed
points.
The melting point and boiling point depend on atmospheric pressure so
the
melting point of ice and the boiling point of water are at standard
atmosphere.
1. Use a thermometer with a scale, e.g. thermometer -10oC
to 110oC
mercury or alcohol, or a tall flask containing coloured water fitted
with a one hole stopper and glass
tube that extends into the bottle. Mark thermometer scales at two
fixed points. The lower fixed point is the temperature of melting ice.
Put the bulb of a thermometer in
crushed ice that is melting. Leave it there for some minutes. Check
that the temperature is 0oC on the calibrated thermometer,
or make a mark on the blank scale or on the
glass tube attached to the small flask. The upper fixed point is the
temperature of boiling water. Put a thermometer in steam immediately
above the surface of boiling
water. Leave it there for some minutes. Check that the thermometer
reads 100oC on the calibrated thermometer, or make a mark on
the blank scale or on the glass tube
attached to the small flask. Divide the distance between the
upper and lower fixed point to obtain marks representing a temperature
difference of 1oC. If you do
the experiment on a mountain at high altitudes the temperature of
boiling water may be below 100oC because of the reduced
atmospheric pressure. If you do the
experiment in a submerged submarine the temperature of boiling water
may be above 100oC. The thermometer in the boiling water
reads exactly 100oC only at sea level
or where the barometer reading is 760 mm of mercury.
22.7.4 Thermometers, 0oC to 100oC
range
First put thermometer into crushed ice after a few minutes observe
if the liquid column in the thermometer is exactly at 0oC.
Take
out the thermometer from the ice wait for a while at the temperature of
surroundings. Put the thermometer on the surface of boiling water the
measuring
bulb is near the heat steam above the surface of water. Wait for a few
minutes observe if the liquid column in the thermometer is at the scale
of 100oC. Note if you live in the region of higher height
above
sea level the boiling point of water there will be lower than 100oC
due to the lower atmospheric pressure. On the contrary in the region of
lower height above sea level the boiling point of water will be higher
than 100oC. Only in height of sea level the boiling point of
water is just 100oC the atmospheric pressure there is 760 mm
Hg.
22.7.5 Thermometers, make a thermometer
Prepare a small glass bottle with a rubber stopper which is punched
a hole and installed a thin glass tube long enough. This is a
thermometer
the small bottle is a measuring bulb the thin glass tube is a pole.
Pour
a few drops of red ink in the water close the stopper to make no air
inside
the bottle. The glass tube must be sealed by stopper as tightly as
possible
until surface of water cannot rise up. Mark 0oC and 100oC
according to the steps above. If it is not possible to measure 0oC
and 100oC because of the limit of level of water and size of
tube,
you can select two suitable temperature points by yourself. However,
but this
time
you must find the temperature by means of a accurate thermometer.
Measure the length between 0oC to 100oC on the
glass
tube divide the length into 10 evenly and mark on the wall of the tube.
(i.e. mark 9 points in same distance each other between 0oC
to 100oC). Write 10oC to 90oC in turn
i.e.
every space is 10oC. You may divide by 10 again between
every
space and mark it. This time every space is 1oC. So a
thermometer
is finished. If you live in the region of higher height above sea level
you should correct fixed point of 100oC according to the
boiling
temperature there.
22.7.6 Thermocouple, thermistor, constantan,
optical
pyrometer
A thermocouple has two different wires or semiconductors joined at
the ends to be a thermoelectric source of EMF, Seebeck effect,
when
the wires are at different temperatures. It is used to detect very
small
differences in temperatures. For more sensitivity, thermocouples are
joined
in series to make a thermopile, pile.
Thermistors are wires used in
electronic
circuits made of metal oxides that decrease in resistance when the
temperature
of the wire increases.
Constantan is an alloy, about 40% nickel and 60 % copper, having high
volume resistivity and negligible temperature coefficient. So
resistance hardly changes with change in temperature. It is used for
resistance wire, also Eureka wire. CrAl (Kranthal) and NiCrm (Nichrome
wire) have very high resistivity. An optical pyrometer is used to
measure very
high
temperatures from the colour of the radiant heat source.
1. Attach a piece of copper and a piece of constantan to two wires.
Heat lead to above its boiling point of 327oC.
Attach the wires to a galvanometer and insert the copper and
constantan
into the boiling lead. The galvanometer can be calibrated to read
temperature
and act as a thermocouple to read the temperature of the molten lead.
22.7.7 Galileo's Thermometer
Use a set of glass spheroid buoys of varying density in a glass
cylinder
arranged so the lowest floating ball represents the temperature.
22.7.8 Air thermometer
See diagram 23.4.9
Select a small medicine bottle with a cork stopper. Bore a hole through
the cork with a cork borer to take a piece of thin glass tubing 30 cm
long.
Put ink in the bottle to cover the end of the tubing, which should be
touching
the bottom of the bottle. Warm the bottle with your hands to make the
air
in the bottle expand, press down on the liquid in the bottle and force
it up the glass tube.